Types of halogenoalkanes . . .
Describes what is meant by primary, secondary and tertiary halogenoalkanes. Essential knowledge if you are to make sense of everything else in this section.
What is nucleophilic substitution? . . .
Includes background material on the bonding in halogenoalkanes, and general mechanisms for their nucleophilic substitution reactions.
Substitution reactions involving hydroxide ions . . .
The mechanisms for the formation of alcohols from halogenoalkanes by reaction with hydroxide ions.
Substitution reactions involving water . . .
The mechanisms for the formation of alcohols from halogenoalkanes by reaction with water.
Substitution reactions involving cyanide ions . . .
The mechanisms for the formation of nitriles from halogenoalkanes by reaction with cyanide ions.
Substitution reactions involving ammonia . . .
The mechanisms for the formation of various sorts of amines from halogenoalkanes by reaction with ammonia. Also includes the reactions between halogenoalkanes and amines.